Since the thorium process is so efficient, the reduced nuclear waste is only about 400 tons from US thorium reactors per year. Pingback: The delusion of thorium â Beyond Nuclear International « nuclear-news, Pingback: The delusion of thorium â Beyond Nuclear International « Antinuclear, The delusion of thorium â Beyond Nuclear International « nuclear-news, The delusion of thorium â Beyond Nuclear International « Antinuclear. Then, it will decay directly to pure U-233. Besides avoiding plutonium, Thorium has additional self-protection from the hard gamma rays emitted test reactor of this type in the 1960s called the Molten Salt Reactor Experiment opposed to fast breeders). All of these isotopes are unstable (radioactive), but only 232 Th is relatively stable with half-life of 14 billion years, which is comparable to the age of the Earth (~4.5×10 9 years). [wikipedia] (MSRE). The problem with Naturally, it takes some time for enough uranium-233 to accumulate to make this particular fission process spontaneously ongoing. While U-233 an excellent fuel in invariably produces some U-232, which decays to Tl-208, which has a 2.6 MeV gamma ray decay mode. But uranium-233 is also very efficient fuel for nuclear weapons. successfully tested. Thorium reactors also produce uranium-232, which decays to an extremely potent high-energy gamma emitter that can penetrate through one metre of concrete, making the handling of this spent nuclear fuel extraordinarily dangerous. Rather, when it is exposed to And very importantly, thorium is not fissile. By absorbed in the fuel in a traditional (thermal) type of reactor. Deploying new uranium-based nuclear reactors would likely happen much more rapidly and at a substantially lower cost. Thorium is a naturally-occurring, slightly radioactive metal discovered in 1828 by the Swedish chemist Jons Jakob Berzelius, who named it after Thor, the Norse god of thunder. (U-235) or reprocessed plutonium (Pu-239) as fuel (in the Uranium-Plutonium cycle), and only a Also, the Up and coming nuclear reactor powerhouses China and India both have substantial reserves of U-235 for reactivity boosts, which means the nuclear fuel resources on Earth can be extended by 2 Thorium-fueled reactors, on the other hand, are fuel-efficient, almost perfectly so, but that comes at the end of a three-phase process, with the first phase shared by thorium ⦠Instead of thorium, a Molten Salt Reactor can use uranium-235 or plutonium waste, from LWR and other reactors. The U.S. tried for 50 years to create thorium reactors, without success. Reprocessing, as conducted at La Hague in France, involves exposing workers to toxic radioisotopes and still produces high volumes of radioactive waste. The Th-U fuel cycle does not irradiate Uranium-238 and therefore does not produce transuranic Thermal breeding is perhaps Thorium cycles exclusively allow thermal breeder reactors (as due to U-232 as discussed above. [wikipedia], Molten Salt Reactor Experiment [wikipedia], Nuclear Power is our gateway to a prosperous future, Liquid Fluoride Thorium Reactor [wikipedia], Special May 2016 Edition of Nuclear Technology on Thorium. Whoâs going to start the startup on these? DR. Thorium is generally accepted as proliferation resistant compared to U-Pu cycles. Current uranium waste is 30,000 tons per year. ... and with a half-life of over 24,000 years, it's tricky to store and dispose of. the thermal spectrum, it is between U-235 and Pu-239 in the fast spectrum. These reactors could Protactinium-233 has a half-life of about 27 days, after which is beta-decays to uranium-233, which is fissile and has impressive properties. U-232 has a 70 year half-life so it takes a long time for these Yes. Thorium reactors work by breeding Th-232 through Protactinium-233 (27.4 day half life) and into Uranium-233, which is fissile. If 232 Th is loaded in the nuclear reactor, the nuclei of 232 Th absorb a neutron and become nuclei of 233 Th. Although thorium advocates say that thorium reactors produce little radioactive waste, they simply produce a different spectrum of waste to those from uranium-235. More neutrons are released per neutronabsorbed in the fuel in a traditional (thermal) type of reactor How is Thorium a Fuel? ... much much safer in terms of what do do with the discarded waste....half-life trivial in comparison. Thorium itself will not split and release energy. The main advantage of thorium is that the waste has a half-life on the ⦠Dr. Helen Mary Caldicott is an Australian physician, author, and anti-nuclear advocate who has founded several associations dedicated to opposing the use of nuclear power, depleted uranium munitions, nuclear weapons, nuclear weapons proliferation, and military action in general. Thorium-bearing minerals and not as much Uranium. Soil contains an average of around 6 parts per million (ppm) of thorium. (Fast-spectrum molten salt reactors (FS-MSR) can use all isotopes of uranium, not just the 0.7% U-235 in natural uranium â with all the safety and stability of MSR.) Also, thoriumâs small nuclear waste only has a half-life of 300 years, not 10,000 years. So, expect this energy source to become a big deal Irradiated Thorium is more dangerously radioactive in the short term. They can actually burn up more radioactive waste than they produce. So for reactors that This week, Dr. Caldicott will receive a Lifetime Achievement Award from the U.S. based Physicians for Social Responsibility, one of the organizations she founded. Thorium advocates say that thorium reactors produce little radioactive waste, however, they simply produce a different spectrum of waste from traditional reactors, including many dangerous isotopes with extremely long half-lives. ⢠In the conversion chain of 232Th to 233U, 233Pa is formed as an intermediate, which has a relatively longer half-life (~27 days) as compared to 239Np (2.35 days) in the uranium fuel cycle thereby requiring longer cooling time of at least one year for completing the decay of 233Pa to 233U. Thorium-232 is useful in breeder reactors because on capturing slow-moving neutrons it decays into fissionable uranium-233. For more information, see the Beyond Nuclear thorium fact sheet. traditional nukes, as well as to fossil fuel obviously), and maybe even cheap. (bigger than uranium) atoms like Plutonium, Americium, Curium, etc. The main whatisnuclear.com website. Thorium reactors are amongst those being suggested at this time. would be much easier to work with. gammas to come back. orders of magnitude without some of the complications of fast reactors. best suited for Molten Salt Reactors, which are discussed on their own page as uranium called U-233, which will readily split and release energy next time it absorbs a neutron. Contribute to davidfetter/website development by creating an account on GitHub. The uranium 233 produced in thorium reactors is contaminated with uranium 232, which is produced through several different neutron absorption pathways. The Th-U cycle This still includes many dangerous alpha and beta emitters, and isotopes with extremely long half-lives, including iodine-129 (half-life of 15.7 million years). We donât have as much experience with Th. Thorium dioxide melts at 550 degrees higher Mini-PRIMER on THE THORIUM CONCEPT. The vast majority of existing or proposed nuclear reactors, however, use enriched uranium This still includes many dangerous alpha and beta emitters, and isotopes with extremely long half-lives, including iodine-129 (half-life of 15.7 million years). Finally, unlike U235, thorium is an efficient neutron absorber and producer. This then emits another electron and anti-neutrino by a second β decay to become U , the fuel: This article originally appeared on Independent Australia and is republished with kind permission of the author. When non-fissionable thorium is mixed with either fissionable plutonium or uranium-235, it captures a neutron and converts to uranium-233, which itself is fissionable. Can Consume Nuclear Waste. Thorium is therefore called fertile, whereas U-233 is called fissile. Before these fuel rods are used, they are only slightly radioactive and may be handled without special shielding. Pa-233 is a pretty strong neutron absorber, so the MSBR (basically the LFTR) has to extract it from the core once it is produced and let it ⦠Nuclear reactor fuel contains ceramic pellets of uranium-235 inside of metal rods. Synthetic isotopes have been prepared; thorium-229 (7,880-year half-life), formed in the decay chain originating in the synthetic actinoid element neptunium, serves as a tracer for ordinary thorium (thorium-232). Chris Coles December 29, 2020 02:56 AM. One especially cool possibility suitable for the thermal-breeding capability of the Th-U fuel cycle Waste Storage It is estimated that it will take over one million dollars per kilogram to dispose of the seriously deadly material. In deep seawaters the isotope 230 Th makes up to 0.04% of natural thorium. Reduced nuclear waste. Online chemical That means no matter how many thorium nuclei are packed together, they can not go critical. stealing spent fuel are largely reduced by Th, but the possibility of the owner of a Th-U reactor Molten-salt reactors are particularly well-suited for the thorium fuel cycle. One-millionth of a gram of plutonium, if inhaled, is carcinogenic.). But Molten salt reactors are amazing. Alvin Weinberg discusses the history of this project in high-quality solid fuel. In order to overcome the initial lack of fissile nuclei in a thorium fuel one may add fissile plutonium to this thorium. Although thorium advocates say that thorium reactors produce little radioactive waste , they simply produce a different spectrum of waste to those from uranium-235, which includes many dangerous alpha and beta emitters and isotopes with extremely long half-lives including technetium 99 - half-life of The half-life of thorium 232, its most abundant isotope, is 14 billion years, or about as old as the universe. The MSRE successfully proved that the concept has merit and can be operated Later, the radioactive fuel would be removed from the reactor and reprocessed to separate out the uranium-233 from the contaminating fission products, and the uranium-233 will then be mixed with more thorium to be placed in another thorium reactor. None of these reactors operate today, but Oak Ridge had a dissolved in a vat of liquid salt. major health concern of long-term nuclear waste. Thorium reactors have long been proposed as a cleaner, safer alternative to nuclear energy. That still means hundreds of years of waste. Four commercial thorium reactors were constructed, all of which failed. has downsides as well. An Energy Department safety investigation recently found a national repository for uranium-233 in a building constructed in 1943 at the Oak Ridge National Laboratory. (LMFBRs) for federal funding and lost out. Hype alert  If someone on the internet told you something unbelievable about Thorium, you might want to check out our Thorium Myths page just to double check it. ability to productively discuss and debate thorium with knowledge of the basics. Of course, it Like Uranium, its properties allow it What about a thorium reactor design?? Thorium doesnât work as well as U-Pu in a fast reactor. temperatures than traditional Uranium dioxide, so very high temperatures are required to produce Thorium is a basic element of nature, like Iron and Uranium. Thorium is a naturally occurring element discovered in 1828 and named after Thor, the Norse god of thunder. It was in poor condition. Investigators reported an environmental release from many of the 1,100 containers could ‘… be expected to occur within the next five years because some of the packages are approaching 30 years of age and have not been regularly inspected.’, The DOE determined that this building had “Deteriorated beyond cost-effective repair and significant annual costs would be incurred to satisfy both current DOE storage standards, and to provide continued protection against potential nuclear criticality accidents or theft of the material.”. As Australia is grappling with the notion of introducing nuclear power into the country, it seems imperative the general public understand the intricacies of these technologies so they can make informed decisions. The Th-U fuel cycle has some intriguing capabilities over the traditional U-Pu cycle. Technetium 99 has a half-life of 300,000 years and iodine 129 a half-life of 15.7 million years. reprocessed, reactors could be fueled without mining any additional Thorium As Nuclear Fuel: the good and the bad, Computing the energy density of nuclear fuel, Molten Salt Reactor Experiment Plutonium has a shorter half-life of about 24,000 years compared to Uranium-235's half-life of just over 700 million years. Half-life of 233 Pa. Thorium 232 is âonlyâ a fertile material and the main problem can be directly in the breeding of fissile uranium 233. The DOE Office of Environmental Management now considers the disposal of this uranium-233 to be ‘an unfunded mandate’. It competed with the liquid metal cooled fast breeder reactors Reactors that use thorium are operating on whatâs called the Thorium-Uranium (Th-U) fuel processing removes fission product neutron poisons and allows online refueling (eliminating the need Uranium 232 has a half-life of 68.9 years, and its daughter radionuclides emit intense, highly penetrating gamma rays that make the material difficult to handle. Plutonium has a shorter half-life of about 24,000 years compared to Uranium-235's half-life ⦠So there is an extraordinarily complex, dangerous and expensive preliminary process to kick-start a fission process in a thorium reactor. One of the biggest is that a much higher fuel burn-up reduces plutonium waste by more than 80%. But Pa-233 has a 27 day half-life, so once the This means that if the fuel is It takes almost a year after the reactor shutdown for all of the protactinium-233 to transform into uranium-233. While uranium enrichment is already very expensive, the reprocessing of spent nuclear fuel from uranium powered reactors is enormously expensive and very dangerous to the workers who are exposed to toxic radioactive isotopes during the process. obtaining bomb material is not. challenging route, one could obtain weapons material. The nuclear industry is quite conservative, Let us start with the basic nuclear properties of Thorium, which present some problems for a reactor designer. through a heat exchanger to bring the heat out to a turbine and make electricity. It is much detail in his autobiography, The First Nuclear So concerns over people One of the biggest is that a much higher fuel burn-up reduces plutonium waste by more than 80%. These transuranics are the A total of two tons of uranium-233 were manufactured in the United States. The 90th element, Thorium, has only one isotope that made it to our planet, Th-232 with a half life of 40 billion years. other things). In the thorium cycle, fuel is formed when Th captures a neutron (whether in a fast reactor or thermal reactor) to become Th . for extended amounts of time. Thorium is very insoluble, which is why it is plentiful in sands but not in seawater, in contrast to uranium. MSR reactors can be an effective way of getting rid of highly radioactive waste. Although thorium advocates say that thorium reactors produce little radioactive waste, they simply produce a spectrum of waste thatâs different from those from uranium 235, which includes many dangerous alpha and beta emitters and isotopes with extremely long half-lives, including technetium 99, with a half-life of 300,000 years, and iodine 129, with a half-life of 15.7 million years. These gamma rays are very hard to shield, requiring more expensive Although thorium advocates say that thorium reactors produce little radioactive waste, they simply produce a spectrum of waste that's different from those from uranium 235, which includes many dangerous alpha and beta emitters and isotopes with extremely long half-lives, including technetium 99, with a half-life of 300,000 years, and iodine 129, with a half-life of 15.7 million years. This makes stealing Thorium based fuels more challenging. handful have used thorium. According to questions we have received, proponents claim that thorium reactors produce less waste and its half-life is âonlyâ a few hundred years rather than thousands. In other words, the thorium nucleus is very stable, with an extremely long shelf-life. Compared to uranium reactors, thorium reactors produce far less waste, and the waste is much less radioactive with a much shorter half-life. When money is at stake, itâs difficult to get people to change from the norm. This is irrelevant for fluid-fueled reactors discussed below. from U-232 itself. avoiding plutonium altogether, thorium cycles are superior in this regard. The longstanding effort to produce these reactors cost the U.S. taxpayers billions of dollars, while billions more dollars are still required to dispose of the highly toxic waste emanating from these failed trials. This material naturally requires similar stringent security measures used for plutonium storage for obvious reasons. cycle. It is found in small amounts in most rocks and soils, where it is about three times more abundant than uranium. Bi-212 also causes problems. This isotope is more hazardous than the U-235 used in conventional reactors, he adds, because it produces U-232 as a side effect (half life: 160,000 years), on top of ⦠year time scale. This is because its parent 238 U is soluble in water, but 230 Th is insoluble and precipitates into the sediment. spent fuel handling and/or reprocessing. Update: See our full page on Molten Salt Reactors for more info. neutrons, it will undergo a series of nuclear reactions until it eventually emerges as an isotope of In nature, virtually all thorium is thorium-232, and has a half-life of about 14.05 billion years. All of the remaining thorium isotopes have half-lives that are less than thirty days and the majority of these have half-lives that are less than ten minutes. (Just kidding, there are Additionally, Th is quite inert, making it difficult to chemically process. No wonder the U.S. nuclear industry gave up on thorium reactors in the 1980s. On this page youâll learn some details about these and leave with the The U.S. Department of Energy (DOE) has already, to its disgrace, ‘lost track’ of 96 kilograms of uranium-233. be extremely safe, proliferation resistant, resource efficient, environmentally superior (to chemically separated shortly after it is produced and removed from the neutron flux (the path to However, contrary to proponentâs claims is the molten salt reactor (MSR), or as one particular MSR is commonly known on the internet, the to shut down for fuel management, etc.). already like 4 startups working on them, and China is developing them as well). Current and exotic designs can theoretically accommodate thorium. It is estimated to be about four times more abundant than uranium in the Earthâs crust. It is, therefore, necessary to mix thorium with either enriched uranium-235 (up to 20 per cent enrichment) or with plutonium â both of which are innately fissionable â to get the process going. The half-life of 233 Th is approximately 21.8 minutes. Although thorium advocates say that thorium reactors produce little radioactive waste, they simply produce a different spectrum of waste to those from uranium-235. Thorium has 6 naturally occurring isotopes. (Photo: Jean-Marie Taillat for WikiMedia Commons), Vast quantities of highly acidic, highly radioactive liquid waste then remain to be disposed of. (Only 6 kilograms of plutonium-239 can fuel a nuclear weapon, while each reactor makes 250 kilos of plutonium per year. Reprocessing spent fuel requires chopping up radioactive fuel rods by remote control, then dissolving them in concentrated nitric acid from which plutonium is precipitated out by complex chemical means. waste is safe for a few times this, weapons are out of the question. Thus, the quantity of U-233 does not change and abundant thorium is consumed in what is called the thorium fuel cycle. The chain reaction heats the salt, which naturally convects Spent fuel is thermally hot as well as highly radioactive and requires remote handling and shielding. Exotic, but Normally, Pa is passed into the fission product waste in the THOREX process, which could have long term ⦠But it is not a fissile isotope. Note, however, that the gammas come from the decay chain of U-232, not Isotope 232 Th belongs to primordial nuclides and ⦠And because of the complexity of problems listed below, thorium reactors are far more expensive than uranium fueled reactors. Thorium fuel is a bit harder to prepare. The spent U-235 from the reactor contains very radioactive isotopes with a half-life of thousands of years, so the waste has to be stored safely for up to 10,000 years. Era [amazon.com], and there is more info available all over the internet. Thorium is only weakly radioactive. Thorium cycles exclusively allow thermal breeder reactors (asopposed to fast breeders). U-233 is Th-232 -> Th-233 -> Pa-233 -> U-233). During the fission process, two things happen to the uraniu⦠in the not-too-distant futureâ¦. Half a century ago, Oak Ridge National Lab in Tennessee successfully ran an experimental reactor that demonstrated feasibility. and the biggest problem with Thorium is that we are lacking in operational experience with it. The thorium-based fuel also comes with other key benefits. Liquid Fluoride Thorium Reactors (LFTR). By this require excellent neutron economy (such as breed-and-burn concepts), Thorium is not ideal. This normally emits an electron and an anti-neutrino ( ν ) by β decay to become Pa . Posted on November 3, 2019 by beyondnuclearinternational. publicly known that even reactor-grade plutonium can be made into a bomb if done carefully. More neutrons are released per neutron melting due to its own heat. However, uranium-238 is long-lived (its half-life, the time it takes for half of it to undergo radioactive decay, is nearly 4.5 billion years) and thorium-234, the isotope that results from the decay of uranium-238, is more radioactive. The half-life of thorium-234 is only 24 days. Thorium exists in nature in a single isotopic form â T⦠heat from these gammas makes weapon fabrication difficult, as it is hard to keep the weapon pit from to be used to fuel a nuclear chain reaction that can run a power plant and make electricity (among She is founding president of Beyond Nuclear. well as in summary below. In these, fuel is not cast into pellets, but is rather After absorbing a neutron, thorium-232 is transmuted into thorium-233, which then beta-decays with a half-life of 22 minutes into protactinium-233, which is chemically distinct from the parent thorium. Thus, Th-U waste will be less toxic on the 10,000+ It takes about the same amount of uranium-233 as plutonium-239 â six kilos â to fuel a nuclear weapon. 4 And with todayâs reactor designs, which in the U.S. are fairly outdated, small disruptions in the process can also lead to catastrophic overheating and meltdowns. plutonium is that it can be chemically separated from the waste and perhaps used in bombs. High-level radioactive waste primarily is uranium fuel that has been used in a nuclear power reactor and is "spent," or no longer efficient in producing electricity. This waste fuel is highly radioactive and the culprits â these high-mass isotopes â have half-lives of many thousands of years. The truth is, thorium is not a naturally fissionable material. IN2P3 Uranium-233 has an extremely long half-life of 159,000 years, but too short for be still present on Earth. The one hypothetical proliferation concern with Thorium fuel though, is that the Protactinium can be It was an unmitigated disaster, as are many other nuclear enterprises undertaken by the nuclear priesthood and the U.S. Government. This means that the contaminants could be chemically separated and the material
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